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RE: PCBs



Chun Yi,

 

Thanks for recommending these. I noticed that the octa- and nona- homolog groups are not included, probably because there are no factors for them within the set of factors you identified. However, it probably makes sense to add these also, as future emission factor profiles may include them. I therefore also recommend adding:

 

53742-07-7  Nonachlorobiphenyl   NNCB, TOT

 

55722-26-4 Octachlorobiphenyl  OCCB, TOT

 

There are also many dioxin and furan congeners that are in the materials table. If we wanted to, we could also include codes for some PCB congeners and/or Arochlor mixtures. See http://www.pic.int/en/CasNumbers/PCB%20CAS%20number.pdf for the possibilities. It may be best to include just the chlorination-level groups for now and we can discuss adding others during our annual dioxin/PAH speciation argument ;-)

 

Regarding adding these emissions to the 2002 inventory: with the exception of the current b(a)p assessment and other egregious errors that might be identified, we have not committed the states/province to updating the 2002 dataset once it has been published. I therefore recommend that we include these factors in the emission factor table and relevant methodologies so that they are included in the 2005 inventory. Any states that would like are welcome to recalculate and update their estimated for 2002 or any prior year. I know that I have seen some emissions data for PCB congeners from other combustion sources as well, particularly open burning. It may serve us well to do a mini-review of this prior to the 2005 inventory to see if there are others that should be included.

 

 

______________________
Jon Dettling
Great Lakes Commission
734-971-9135
dettling@glc.org


From: owner-airtoxics@great-lakes.net [mailto:owner-airtoxics@great-lakes.net] On Behalf Of Wu, Chun Yi
Sent: Thursday, August 10, 2006 5:35 PM
To: Airtoxics
Subject: RE: PCBs

 

I think it is better to have new codes in RAPIDS since the toxicity profile for these congeners may be widely different.

 

The suggested RAPIDS codes with the same convention as PCDDs and PCDFs are:

 

CAS#

Pollutant

Suggested RAPIDS codes

7012-37-5

2,4,4'-Trichlorobiphenyl

TRICB,244

2051-60-7

2-Monochlorobiphenyl

MONOCB,2

2051-24-3

Decachlorobiphenyl

DECACB

2050-68-2

Dichlorobiphenyl

DICB,TOT

28655-71-2

Heptachlorobiphenyls, Total

HPCB,TOT

26601-64-9

Hexachlorobiphenyls, Total

HXCB,TOT

25429-29-2

Pentachlorobiphenyls, Total

PECB,TOT

26914-33-0

Tetrachlorobiphenyls, Total            

TCB,TOT

 

To include emissions of these compounds in the repository database for MN we need to have following steps:

 

  1. Create new RAPIDS codes
  2. Enter state or generic emission factors for them
  3. Calculate emissions
  4. Export data from RAPIDS
  5. Import data to the repository

 

My question is should we do all these for the 2002 EI or we start to include them in the 2005 EI?

 

 

 

Chun Yi

 

-----Original Message-----
From: owner-airtoxics@great-lakes.net [mailto:owner-airtoxics@great-lakes.net] On Behalf Of Jon Dettling
Sent: Thursday, August 10, 2006 2:42 PM
To: 'Airtoxics'
Subject: RE: PCBs

 

Chun Yi,

 

I think these are certainly emissions that fall within the scope of our target list and so we should take what steps are necessary to include them. It seems to me there are two ways to go about this:

 

-convert these emission factors to total PCBs and estimate emissions on that basis

-include the appropriate pollutant codes and map them to total PCBs for reporting

 

My guess is that states may differ on how they’d like to do this. I don’t see a reason we can’t make the modifications to accommodate those who would like to do the second by adding RAPIDS codes for the congener groups to the materials table and map them to total PCBs for reporting. My guess is that you fall in this group. Would you like to take on the task of recommending a set of material codes for the group to consider?

 

Jon

______________________
Jon Dettling
Great Lakes Commission
734-971-9135
dettling@glc.org


From: owner-airtoxics@great-lakes.net [mailto:owner-airtoxics@great-lakes.net] On Behalf Of Wu, Chun Yi
Sent: Thursday, August 10, 2006 12:51 PM
To: Airtoxics
Subject: RE: PCBs

 

 

-----Original Message-----
From: Wu, Chun Yi
Sent: Thursday, August 10, 2006 11:49 AM
To: Airtoxics
Subject: RE: PCBs

 

The emission factors for PCBs are attached.  All these factors were created after FIRE6.23 with an EPA date of 9/1/03.  All these emission factors are for External Combustion Boilers that burn Wood/Bark Waste.

 

Chun Yi

 

-----Original Message-----
From: owner-airtoxics@great-lakes.net [mailto:owner-airtoxics@great-lakes.net] On Behalf Of Cabrera-Rivera, Orlando
Sent: Thursday, August 10, 2006 9:32 AM
To: Wu, Chun Yi; Airtoxics
Subject: RE: PCBs

 

Chun Yi,

 

Thanks for the information. I believe that it is worth looking into this. We may want to find out a few things. 1 What are the SCCs associated with these factors?, 2) Do factors exists for total PCBs for the same SCCs? 3) Do any of the states collect data on these emissions or these processes?

 

Orlando

 


From: owner-airtoxics@great-lakes.net [mailto:owner-airtoxics@great-lakes.net] On Behalf Of Wu, Chun Yi
Sent: Thursday, August 10, 2006 8:20 AM
To: Airtoxics
Subject: PCBs

FIRE contains emission factors for the following pollutants, PCB congeners.  However, RAPIDS does not have material cods for them.  Do we want to create new material codes?

 

CAS#                        Pollutant

7012-37-5                   2,4,4-Trichlorobiphenyl

2051-24-3                   Decachlorobiphenyl

2050-68-2                   Dichlorobiphenyl

28655-71-2                 Heptachlorobiphenyls, Total

26601-64-9                 Hexachlorobiphenyls, Total

25429-29-2                 Pentachlorobiphenyls, Total

26914-33-0                 Tetrachlorobiphenyls, Total            

 

 

Chun Yi