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RE: PCBs



Chun,

Happy New Year.

I am adding the HAPS your sent me to the NEI pollutant code list and
have some questions for you.  See the table below.  Which pollutant did
you mean to add?  You used the CAS # 2050-68-2 which is for
4,4'Dichlorobiphenyl , But you identified the PCB as dichlorobiphenyl
which has a CAS number of 25512-42-9.

thanks

anne
                                                                         
                                                                         
                                                                         
                                                                         
                                                                         
                                                                         
                                                                         
                                                                         
                                                                         
                                                                         
                                                                         
                                                                         
                                                                         
                                                                         
  Systematic Name                                                        
                EPA Registry Name                                        
                              Classification                             
                                            CAS Number                   
                                                                     TSN 
                                                                      IC 
                                                                      TV 
             EPA ID                                                      
                          Compare?                                       
  1,1'-Biphenyl, dichloro-                                               
                Dichlorobiphenyl                                         
                              Chemical                                   
                                            25512-42-9                   
                                                                         
                                                                         
                                                                         
                                                                         
                                             |------|                    
                                             | [ ]  |                    
                                             |------|                    
                                                                         
                                                                         
  1,1'-Biphenyl, 4,4'-dichloro-                                          
                4,4'-Dichlorobiphenyl                                    
                              Chemical                                   
                                            2050-68-2                    
                                                                         
                                                                         
                                                                         
                                                                         
                                             |------|                    
                                             | [ ]  |                    
                                             |------|                    
                                                                         
                                                                         
                                                                         
                                                                         
                                                                         
                                                                         
                                                                         
                                                                         
                                                                         

                                                                         
                                                                         
                                                                         
                                                                         
                                                                         
                                                                         
                                                                         
                                                                         
                                                                         
                                                                         





                                                                        
             "Wu, Chun Yi"                                              
             <Chun.Yi.Wu@stat                                           
             e.mn.us>                                                To 
             Sent by:                 Airtoxics                         
             owner-airtoxics@         <airtoxics@great-lakes.net>       
             great-lakes.net                                         cc 
                                                                        
                                                                Subject 
             08/10/2006 05:34         RE: PCBs                          
             PM                                                         
                                                                        
                                                                        
                                                                        
                                                                        
                                                                        




I think it is better to have new codes in RAPIDS since the toxicity
profile for these congeners may be widely different.

The suggested RAPIDS codes with the same convention as PCDDs and PCDFs
are:



                                                                   
 CAS#            Pollutant                   Suggested RAPIDS      
                                             codes                 
                                                                   
 7012-37-5       2,4,4'-Trichlorobiphenyl    TRICB,244             
                                                                   
 2051-60-7       2-Monochlorobiphenyl        MONOCB,2              
                                                                   
 2051-24-3       Decachlorobiphenyl          DECACB                
                                                                   
 2050-68-2       Dichlorobiphenyl            DICB,TOT              
                                                                   
 28655-71-2      Heptachlorobiphenyls, Total HPCB,TOT              
                                                                   
 26601-64-9      Hexachlorobiphenyls, Total  HXCB,TOT              
                                                                   
 25429-29-2      Pentachlorobiphenyls, Total PECB,TOT              
                                                                   
 26914-33-0      Tetrachlorobiphenyls, Total TCB,TOT               
                                                                   
                                                                   



To include emissions of these compounds in the repository database for
MN we need to have following steps:

   1. Create new RAPIDS codes
   2. Enter state or generic emission factors for them
   3. Calculate emissions
   4. Export data from RAPIDS
   5. Import data to the repository

My question is should we do all these for the 2002 EI or we start to
include them in the 2005 EI?



Chun Yi

      -----Original Message-----
      From: owner-airtoxics@great-lakes.net
      [mailto:owner-airtoxics@great-lakes.net] On Behalf Of Jon Dettling
      Sent: Thursday, August 10, 2006 2:42 PM
      To: 'Airtoxics'
      Subject: RE: PCBs

      Chun Yi,

      I think these are certainly emissions that fall within the scope
      of our target list and so we should take what steps are necessary
      to include them. It seems to me there are two ways to go about
      this:

      -convert these emission factors to total PCBs and estimate
      emissions on that basis
      -include the appropriate pollutant codes and map them to total
      PCBs for reporting

      My guess is that states may differ on how they’d like to do this.
      I don’t see a reason we can’t make the modifications to
      accommodate those who would like to do the second by adding RAPIDS
      codes for the congener groups to the materials table and map them
      to total PCBs for reporting. My guess is that you fall in this
      group. Would you like to take on the task of recommending a set of
      material codes for the group to consider?

      Jon


      ______________________
      Jon Dettling
      Great Lakes Commission
      734-971-9135
      dettling@glc.org

      From: owner-airtoxics@great-lakes.net
      [mailto:owner-airtoxics@great-lakes.net] On Behalf Of Wu, Chun Yi
      Sent: Thursday, August 10, 2006 12:51 PM
      To: Airtoxics
      Subject: RE: PCBs


            -----Original Message-----
            From: Wu, Chun Yi
            Sent: Thursday, August 10, 2006 11:49 AM
            To: Airtoxics
            Subject: RE: PCBs

            The emission factors for PCBs are attached.  All these
            factors were created after FIRE6.23 with an EPA date of
            9/1/03.  All these emission factors are for External
            Combustion Boilers that burn Wood/Bark Waste.

            Chun Yi

                  -----Original Message-----
                  From: owner-airtoxics@great-lakes.net
                  [mailto:owner-airtoxics@great-lakes.net] On Behalf Of
                  Cabrera-Rivera, Orlando
                  Sent: Thursday, August 10, 2006 9:32 AM
                  To: Wu, Chun Yi; Airtoxics
                  Subject: RE: PCBs

                  Chun Yi,

                  Thanks for the information. I believe that it is worth
                  looking into this. We may want to find out a few
                  things. 1 What are the SCCs associated with these
                  factors?, 2) Do factors exists for total PCBs for the
                  same SCCs? 3) Do any of the states collect data on
                  these emissions or these processes?

                  Orlando


                        From: owner-airtoxics@great-lakes.net
                        [mailto:owner-airtoxics@great-lakes.net] On
                        Behalf Of Wu, Chun Yi
                        Sent: Thursday, August 10, 2006 8:20 AM
                        To: Airtoxics
                        Subject: PCBs
                        FIRE contains emission factors for the following
                        pollutants, PCB congeners.  However, RAPIDS does
                        not have material cods for them.  Do we want to
                        create new material codes?

                        CAS#                        Pollutant
                        7012-37-5
                        2,4,4-Trichlorobiphenyl
                        2051-24-3                   Decachlorobiphenyl
                        2050-68-2                   Dichlorobiphenyl
                        28655-71-2                 Heptachlorobiphenyls,
                        Total
                        26601-64-9                 Hexachlorobiphenyls,
                        Total
                        25429-29-2                 Pentachlorobiphenyls,
                        Total
                        26914-33-0                 Tetrachlorobiphenyls,
                        Total


                        Chun Yi
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